18.09.2006
Deportivo La Coruna [2 - 0] Villarreal 1-0 & 2-0 Capdevila
Recreativo Huelva [0 - 1] Levante 0-1 Alexis
Valencia CF [2 - 0] Getafe 1-0 Morientes 2-0 Vincente
Real Zaragoza [2 - 0] RCD Mallorca 1-0 Ewerthon 2-0 Sergio Garcia
Real Madrid [2 - 0] Real Sociedad 1-0 Reyes 2-0 Bechham
Racing Santander [0 - 3] Barcelona CF 0-1 Eto`o 0-2 Guily 0-3 Ronaldinho
CA Osasuna [2 - 0] Gimnastic 1-0 Webo 2-0 Milosevic
Espanyol Barcelona [2 - 1] Celta de Vigo 1-0 Moises 1-1 Cannobio 2-1 Jonathan
Athletic Bilbao [1 - 4] Atletico Madrid 0-1 Maxi Rodriguez 0-2 Petrov 0-3 Agüero 1-3 Martinez 1-4 Galletti
FC Sevilla [3 - 2] Real Betis Sevilla 1-0 Kanoute 1-1 & 1-2 Sobis 2-2 Kanoute 3-2 Renato